9
9
Anodic Current

Anodic Current

by | Jan 4, 2016 | Uncategorized

In the context of electroanalytical chemistry, the terms anode, anodic current, and oxidation are closely related.

An anodic current is the flow of electrical charge (usually carried by electrons) into a working electrode from a second phase (usually an electrolyte solution) as a result of the oxidation of one or more species in the second phase.

As an example, consider a platinum working electrode immersed in an acidic solution of iron(II) chloride. If the platinum working electrode is poised at a sufficiently positive potential, any iron(II) cations in the vicinity of the electrode surface will lose an electron and be oxidized to iron(III) cations according to the following half reaction:

Fe^{2+} \rightleftharpoons Fe^{3+} + e^-

In this case, the flow of electrons into the working electrode as a result of the oxidation of the iron(II) cations is an anodic current.


Related Terms: anode, oxidation

Antonyms: cathodic current