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Honeycomb Spectroelectrochemistry Cell Kit

Part Number
AKSTCKIT3
Honeycomb Spectroelectrochemistry Cell Beam Path

Our unique UV/Vis spectroelectrochemical cell features a patterned “honeycomb” electrode which mounts easily inside a thin-layer quartz cuvette. A special cuvette cap securely holds the honeycomb electrode card and a separate reference electrode in the proper position within the cuvette.

  • 1.7 mm electrode path length
  • 12.5 x 12.5 x 45.0 mm3 cuvette dimensions 
  • Compatible in aqueous and non-aqueous electrolyte
  • Universal Specialty Cell Connection Kit (included) enables cell kit compatibility with ANY potentiostat

See “Description” tab below for additional information.
[alert color=”blue” icon=”info-circle”]The Honeycomb Spectroelectrochemical Cell Kit (AKSTCKIT3) includes 1 quartz cuvette, 1 cell cap, 1 platinum honeycomb electrode, 2 gold honeycomb electrodes, Universal Specialty Cell Connection Kit, and a low profile Ag/AgCl reference electrode.  Cell cables are sold separately.[/alert]

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Spectroelectrochemistry
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References
Complete Spectroelectrochemistry Cell Kit: The Honeycomb Spectroelectrochemical Cell Kit (AKSTCKIT3) includes 1 quartz cuvette, 1 cell cap, 1 platinum honeycomb electrode, 2 gold honeycomb electrodes, the Universal Specialty Cell Connection Kit, and a low profile Ag/AgCl reference electrode.  Our honeycomb electrode chip contains an onboard working, counter and reference electrode.  If an alternative reference electrode is needed, we offer a cell cable with a separate reference breakout lead (RRTPE05 for the WaveNow Series and ACP2E09 for the WaveDriver series) used with the WaveNow and WaveDriver respectively where a separate low profile reference electrode fits into the cell cap.  Click here for low profile reference electrodes! Electrode Design: The working electrode is perforated with a honeycomb pattern of holes which allow light to pass through the electrode. The active surface of the working electrode includes a metal coating along the inner walls of the holes. As light passes through the holes, the beam grazes the walls of each hole.  Normally the path length of the electrochemically generated species is the diffusion layer near the surface of the electrode.  With our honeycomb design the effective path length is the length of the honeycomb card (1.7 mm).  As a result, molecules with low extinction coefficients are more easily detectable.  Our quartz cuvette is slotted to fit the honeycomb electrode card.  The slot also prevents electrogenerated species from diffusing away from the electrode during a spectroelectrochemistry experiment, further improving UV/Vis absorbance. Universal Compatibility:  The honeycomb electrode is screen printed on a ceramic card, allowing it to be used for both aqueous and non-aqueous solvents.  The dimensions of our slotted quartz cuvette is 12.5 x 12.5 x 45.0 mm3, which is the standard size for most UV/Vis spectrometer cuvette holders.  While Pine Research offers a unique cable that connects the mini-B USB of the honeycomb cell to our WaveNow and WaveDriver potentiostats, we also include a Universal Specialty Cell Connection kit with each Honeycomb cell, for use with any potentiostat.
When possible, we add published articles, theses and dissertations, and books to our references library. When we know this product has been used, we will include it in this list below. If you have a reference where our product was used and it's not in this list, please contact us with the details and we will add it.
  1. H Jeon, H Jo, S Seo, SJ Lee, SJ Yoon, D Han In-situ spectroelectrochemical analysis: Irreversible deformation of cesium lead bromide Perovskite Quantum Dots in SiOx matrices. Sensors and Actuators Reports, 2024, 8, 100208.
  2. Milunovic et al. Copper(II) Complexes with Isomeric Morpholine-Substituted 2-Formylpyridine Thiosemicarbazone Hybrids as Potential Anticancer Drugs Inhibiting Both Ribonucleotide Reductase and Tubulin Polymerization: The Morpholine Position Matters. Journal of Medicinal Chemistry, 2024, 67, 9069-9090.
  3. Kovács et al. Complex formation of ML324, the histone demethylase inhibitor, with essential metal ions: Relationship between solution chemistry and anticancer activity. Journal of Inorganic Biochemistry, 2024, 255, 112540.
  4. Gemünde et al. Redox mediator interaction with Cupriavidus necator – spectroelectrochemical online analysis. Electrochemistry Communications, 2024, 162, 107705.
  5. Portela et al. Widespread extracellular electron transfer pathways for charging microbial cytochrome OmcS nanowires via periplasmic cytochromes PpcABCDE. Nature Communications, 2024, 15, 2434.
  6. Lee et al. In Situ Spectroelectrochemical Investigation of Perovskite Quantum Dots for Tracking Their Transformation. Frontiers in Energy Research, 2024, 8, -.
  7. Brady, Matthew. Fundamental Insights into Dye-Sensitized Interfaces for Solar Fuels Production. Ph.D. Dissertation, University of North Carolina at Chapel Hill (Chapel Hill, NC), 2019.
  8. Shova et al. Dinuclear manganese(III) complexes with bioinspired coordination and variable linkers showing weak exchange effects: a synthetic, structural, spectroscopic and computation study. Dalton Transactions, 2024, , .
  9. E. Büchel et al. cis -Tetrachlorido-bis(indazole)osmium(IV) and its osmium(III) analogues: paving the way towards the cis -isomer of the ruthenium anticancer drugs KP1019 and/or NKP1339. Dalton Transactions, 2024, 46, 11925-11941.
  10. Shova et al. A five-coordinate manganese(III) complex of a salen type ligand with a positive axial anisotropy parameter D. Dalton Transactions, 2024, 46, 11817-11829.
  11. Kennedy et al. Synthesis and characterization of the gold dithiolene monoanion, (Bu4N)[Au(pdt=2,3-pyrazinedithiol)2]. Polyhedron, 2024, 103, 100–104.
  12. Pourrieux et al. Redox-induced linkage isomerization detected in [Ru(NH3)5(NVF)](PF6)2(NVF=N-vinylformamide). Inorganic Chemistry Communications, 2024, 66, 90-93.
  13. Yang et al. Reduction potential and heme-pocket polarity in low potential cytochrome b5 of Giardia intestinalis. Journal of Inorganic Biochemistry, 2024, 158, 110–114.
  14. Pazdzior et al. Low reduction potential cytochrome b5 isotypes of Giardia intestinalis. Experimental Parasitology, 2024, 157, 197-201.
  15. Zhong et al. Redox-dependent stability, protonation, and reactivity of cysteine-bound heme proteins. Proceedings of the National Academy of Sciences, 2024, 111, E306—-E315.
  16. Thomsen et al. Electrochemical Activation of Cp* Iridium Complexes for Electrode-Driven Water-Oxidation Catalysis. Journal of the American Chemical Society, 2024, 136, 13826–13834.
  17. Carpenter et al. Structure and redox properties of the diheme electron carrier cytochrome c4 from Pseudomonas aeruginosa. Journal of Inorganic Biochemistry, 2020, 203, 110889.
  18. Balaraman et al. Electrochemical studies of cobalt(II) diphenylazodioxide complexes. Inorganica Chimica Acta, 2020, 501, 119277.
  19. Darvasiová et al. Spectroelectrochemical, photochemical and theoretical study of octaazamacrocyclic nickel(II) complexes exhibiting unusual solvent-dependent deprotonation of methylene group. Electrochimica Acta, 2019, 326, 135006.
  20. Zheng et al. Highly efficient stepwise electrochemical degradation of antibiotics in water by in situ formed Cu(OH)2 nanowires. Applied Catalysis B: Environmental, 2019, 256, 117824.
  21. Dobrov et al. Nickel(II) Complexes with Redox Noninnocent Octaazamacrocycles as Catalysts in Oxidation Reactions. Inorganic Chemistry, 2019, 58, 11133-11145.
  22. Ohui et al. Redox-Active Organoruthenium(II)– and Organoosmium(II)–Copper(II) Complexes, with an Amidrazone–Morpholine Hybrid and [CuICl2]− as Counteranion and Their Antiproliferative Activity. Organometallics, 2019, 38, 2307-2318.
  23. Ohui et al. New Water-Soluble Copper(II) Complexes with Morpholine–Thiosemicarbazone Hybrids: Insights into the Anticancer and Antibacterial Mode of Action. Journal of Medicinal Chemistry, 2019, 62, 512-530.
  24. Schorsch et al. A unique ferredoxin acts as a player in the low-iron response of photosynthetic organisms. Proceedings of the National Academy of Sciences, 2018, 115, E12111-E12120.
  25. Kellett et al. Resolving orbital pathways for intermolecular electron transfer. Nature Communications, 2018, 9, 4916.
  26. Orlowska et al. NO Releasing and Anticancer Properties of Octahedral Ruthenium–Nitrosyl Complexes with Equatorial 1H-Indazole Ligands. Inorganic Chemistry, 2018, 57, 10702-10717.
  27. Piechota et al. Optical Intramolecular Electron Transfer in Opposite Directions through the Same Bridge That Follows Different Pathways. Journal of the American Chemical Society, 2018, 140, 7176-7186.
  28. Barr et al. Charge Rectification at Molecular Nanocrystalline TiO2 Interfaces: Overlap Optimization To Promote Vectorial Electron Transfer. The Journal of Physical Chemistry C, 2016, 120, 27173-27181.
  29. Adams and Schmehl Micellar Effects on Photoinduced Electron Transfer in Aqueous Solutions Revisited: Dramatic Enhancement of Cage Escape Yields in Surfactant Ru(II) Diimine Complex/[Ru(NH3)6]2+ Systems. Langmuir, 2016, 32, 8598–8607.
  30. Liang et al. Probing Energy and Electron Transfer Mechanisms in Fluorescence Quenching of Biomass Carbon Quantum Dots. ACS Applied Materials & Interfaces, 2016, 8, 17478-17488.
  31. Salpage et al. Structural, electrochemical and photophysical properties of an exocyclic di-ruthenium complex and its application as a photosensitizer. Dalton Transactions, 2016, 45, 9601-9607.
  32. Al-Yasari, Ahmed. Synthesis, non-linear optical and electrochemical properties of novel organoimido polyoxometalate derivatives. Ph.D. Dissertation, University of East Anglia (Norwich, United Kingdom), 2016-02.
  33. DiMarco et al. Cation-Dependent Charge Recombination to Organic Mediators in Dye-Sensitized Solar Cells. Journal of Physical Chemistry C, 2015, 119, 21599–21604.
  34. Zhao et al. Understanding the Effect of Monomeric Iridium(III/IV) Aquo Complexes on the Photoelectrochemistry of IrOx·nH2O-Catalyzed Water-Splitting Systems. Journal of the American Chemical Society, 2015, 137, 8749–8757.
  35. Bischof et al. Quantitative Assessment of the Connection between Steric Hindrance and Electronic Coupling in 2,5-Bis(alkoxy)benzene-Based Mixed-Valence Dimers. Journal of Physical Chemistry C, 2014, 118, 12693–12699.
  36. Navarathne and Skene Towards Electrochromic Devices Having Visible Color Switching Using Electronic Push–Push and Push–Pull Cinnamaldehyde Derivatives. ACS Applied Materials & Interfaces, 2013, 5, 12646–12653.
  37. King et al. Metalloproteins Diversified: The Auracyanins Are a Family of Cupredoxins That Stretch the Spectral and Redox Limits of Blue Copper Proteins. Biochemistry, 2013, 52, 8267–8275.
  38. Kim et al. Synthesis and characterization of ruthenium polypyridyl complexes with hydroxypyridine derivatives: effect of protonation and ethylation at the pyridyl nitrogen. Dalton Transactions, 2013, 42, 15656-15662.
  39. Palmer and Lancaster Molecular Redox: Revisiting the Electronic Structures of the Group 9 Metallocorroles. Inorganic Chemistry, 2012, 51, 12473–12482.
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